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Direct Generation of Acyclic Polypropionate Stereopolyads via Double Diastereo- and Enantioselective Iridium Catalyzed Crotylation of 1,3-Diols: Beyond Stepwise Carbonyl Addition in Polyketide Construction
Under the conditions of transfer hydrogenation employing a cyclometallated iridium catalyst (R)-I derived from [Ir(cod)Cl](2), allyl acetate, 4-cyano-3-nitrobenzoic acid and the chiral phosphine ligand (R)-SEGPHOS, α-methyl allyl acetate engages 1,3-propanediol 1a and 2-methyl-1,3-propanediol 1b in...
Gorde:
| Egile Nagusiak: | , , |
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| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2011
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3154980/ https://ncbi.nlm.nih.gov/pubmed/21739988 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja204570w |
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