Lataa...

Direct Generation of Acyclic Polypropionate Stereopolyads via Double Diastereo- and Enantioselective Iridium Catalyzed Crotylation of 1,3-Diols: Beyond Stepwise Carbonyl Addition in Polyketide Construction

Under the conditions of transfer hydrogenation employing a cyclometallated iridium catalyst (R)-I derived from [Ir(cod)Cl](2), allyl acetate, 4-cyano-3-nitrobenzoic acid and the chiral phosphine ligand (R)-SEGPHOS, α-methyl allyl acetate engages 1,3-propanediol 1a and 2-methyl-1,3-propanediol 1b in...

Täydet tiedot

Tallennettuna:
Bibliografiset tiedot
Päätekijät: Gao, Xin, Han, Hoon, Krische, Michael J.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2011
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC3154980/
https://ncbi.nlm.nih.gov/pubmed/21739988
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja204570w
Tagit: Lisää tagi
Ei tageja, Lisää ensimmäinen tagi!