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Direct Generation of Acyclic Polypropionate Stereopolyads via Double Diastereo- and Enantioselective Iridium Catalyzed Crotylation of 1,3-Diols: Beyond Stepwise Carbonyl Addition in Polyketide Construction

Under the conditions of transfer hydrogenation employing a cyclometallated iridium catalyst (R)-I derived from [Ir(cod)Cl](2), allyl acetate, 4-cyano-3-nitrobenzoic acid and the chiral phosphine ligand (R)-SEGPHOS, α-methyl allyl acetate engages 1,3-propanediol 1a and 2-methyl-1,3-propanediol 1b in...

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Detalhes bibliográficos
Main Authors: Gao, Xin, Han, Hoon, Krische, Michael J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3154980/
https://ncbi.nlm.nih.gov/pubmed/21739988
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja204570w
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