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Highly Selective Coupling of Alkenes and Aldehydes Catalyzed by NHC–Ni–P(OPh)(3): Synergy Between a Strong σ-Donor and a Strong π-Acceptor

Both a strong electron donor (IPr) and a strong electron acceptor (P(OPh)(3)) are necessary for a highly selective, nickel-catalyzed coupling reaction between alkenes, aldehydes, and silyltriflates. Without the phosphite, catalysis is not observed and several side reactions are observed. The phosphi...

詳細記述

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書誌詳細
主要な著者: Ho, Chun-Yu, Jamison, Timothy F.
フォーマット: Artigo
言語:Inglês
出版事項: 2007
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3148196/
https://ncbi.nlm.nih.gov/pubmed/17154217
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200603907
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