Electronically Driven Regioselective Iridium‐Catalyzed C−H Borylation of Donor‐π‐Acceptor Chromophores Containing Triarylboron Acceptors

We observed a surprisingly high electronically driven regioselectivity for the iridium‐catalyzed C−H borylation of donor‐π‐acceptor (d‐π‐A) systems with diphenylamino (1) or carbazolyl (2) moieties as the donor, bis(2,6‐bis(trifluoromethyl)phenyl)boryl (B((F)Xyl)(2)) as the acceptor, and 1,4‐phenyle...

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Publicado en:Chemistry
Autores principales: Rauch, Florian, Krebs, Johannes, Günther, Julian, Friedrich, Alexandra, Hähnel, Martin, Krummenacher, Ivo, Braunschweig, Holger, Finze, Maik, Marder, Todd B.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497074/
https://ncbi.nlm.nih.gov/pubmed/32510684
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002348
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