N‐Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–π–A Compounds

N‐heterocyclic olefins (NHOs), relatives of N‐heterocyclic carbenes (NHCs), exhibit high nucleophilicity and soft Lewis basic character. To investigate their π‐electron donating ability, NHOs were attached to triarylborane π‐acceptors (A) giving donor (D)–π–A compounds 1–3. In addition, an enamine π...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: He, Jiang, Rauch, Florian, Friedrich, Alexandra, Sieh, Daniel, Ribbeck, Tatjana, Krummenacher, Ivo, Braunschweig, Holger, Finze, Maik, Marder, Todd B.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6899742/
https://ncbi.nlm.nih.gov/pubmed/31471986
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903118
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