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Highly Selective Coupling of Alkenes and Aldehydes Catalyzed by NHC–Ni–P(OPh)(3): Synergy Between a Strong σ-Donor and a Strong π-Acceptor
Both a strong electron donor (IPr) and a strong electron acceptor (P(OPh)(3)) are necessary for a highly selective, nickel-catalyzed coupling reaction between alkenes, aldehydes, and silyltriflates. Without the phosphite, catalysis is not observed and several side reactions are observed. The phosphi...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2007
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3148196/ https://ncbi.nlm.nih.gov/pubmed/17154217 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200603907 |
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