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Ni(NHC)]-Catalyzed Cycloaddition of Diynes and Tropone: Apparent Enone Cycloaddition Involving an 8π Insertion
[Image: see text] A Ni/N-heterocyclic carbene catalyst couples diynes to the C(α)–C(β) double bond of tropone, a type of reaction that is unprecedented for metal-catalyzed cycloadditions with aromatic tropone. Many different diynes were efficiently coupled to afford [5–6–7] fused tricyclic products,...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4291811/ https://ncbi.nlm.nih.gov/pubmed/25416006 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5105206 |
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