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Catalytic Asymmetric C–H Insertions of Rhodium(II) Azavinyl Carbenes
A highly efficient enantioselective C–H insertion of azavinyl carbenes into unactivated alkanes has been developed. These transition metal carbenes are directly generated from readily available and stable 1-sulfonyl-1,2,3-triazoles in the presence of chiral Rh(II) carboxylates and are used for C–H f...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3142877/ https://ncbi.nlm.nih.gov/pubmed/21619004 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja202969z |
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