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Iridium-catalyzed Arene ortho-Silylation by Formal Hydroxyl-directed C-H Activation
A strategy for the ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives has been developed in which a hydroxyl group formally serves as the directing element for Ir-catalyzed arene C-H bond activation. One-pot generation of a (hydrido)silyl ether from the carbonyl compound or...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3135680/ https://ncbi.nlm.nih.gov/pubmed/21077625 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1086547 |
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