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Efficient, scalable asymmetric synthesis of an epoxy quinol via Noyori desymmetrization of a meso diketone
Epoxy quinol 1a was prepared on a multi-gram scale by Noyori transfer hydrogenative desymmetrization of the readily available meso epoxy diketone 4. Although the intrinsic enantioselectivity for the desymmetrization was modest (82:18 er at 4% conversion), a highly enantiopure product (99.6:0.4 er) c...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3131412/ https://ncbi.nlm.nih.gov/pubmed/21743778 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetasy.2011.04.022 |
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