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Desymmetrization of meso-2,5-Diallylpyrrolidinyl Ureas via Asymmetric Pd-Catalyzed Carboamination Reactions. Stereocontrolled Synthesis of Bicyclic Ureas
The stereoselective synthesis of fused bicyclic ureas 8 is accomplished via enantioselective Pd-catalyzed desymmetrizing carboamination reactions of meso-2,5-diallylpyrroldinyl urea 7c. The reactions generate a C–N bond, a C–C bond, and afford products bearing three stereocenters with good diastereo...
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| Autores principales: | , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2013
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3812936/ https://ncbi.nlm.nih.gov/pubmed/23824590 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201302720 |
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