Asymmetric desymmetrization of meso-diols by C(2)-symmetric chiral 4-pyrrolidinopyridines

In this work we developed C(2)-symmetric chiral nucleophilic catalysts which possess a pyrrolidinopyridine framework as a catalytic site. Some of these organocatalysts effectively promoted asymmetric desymmetrization of meso-diols via enantioselective acylation.

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Detalhes bibliográficos
Main Authors: Schedel, Hartmut, Kan, Keizo, Ueda, Yoshihiro, Mishiro, Kenji, Yoshida, Keisuke, Furuta, Takumi, Kawabata, Takeo
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2012
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Full Research Paper
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3511012/
https://ncbi.nlm.nih.gov/pubmed/23209512
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.203
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