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Chiral Pentacarboxycyclopentadiene-Based Brønsted Acid-Catalyzed Enantioselective Desymmetrization of Meso-Epoxides by 2-Mercaptobenzothiazoles

[Image: see text] Enantioselective desymmetrization of meso-epoxides by 2-mercaptobenzothiazoles was realized by using the pentacarboxycyclopentadiene-based chiral Brønsted acid in combination of N-isopropylaniline as amine additive to give up to 90.5:9.5 er of the ring opening products.

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Detalhes bibliográficos
Publicado no:ACS Omega
Main Authors: Yuan, Chao, Li, Jun, Li, Pingfan
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2018
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6644688/
https://ncbi.nlm.nih.gov/pubmed/31458851
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.8b01207
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