Lithium BINOL Phosphate Catalyzed Desymmetrization of meso-Epoxides with Aromatic Thiols

[Image: see text] A highly enantioselective method for desymmetrization of meso-epoxides using thiols is reported. This is the first example of epoxide activation achieved using metal BINOL phosphates. The reaction has a broad scope in terms of epoxide substrates and aromatic thiol nucleophiles. The...

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Detaylı Bibliyografya
Yayımlandı:Org Lett
Asıl Yazarlar: Ingle, Gajendrasingh, Mormino, Michael G., Antilla, Jon C.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: American Chemical Society 2014
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC4227545/
https://ncbi.nlm.nih.gov/pubmed/25317934
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol502527q
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