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Unprecedented Directing Group Ability of Cyclophanes in Arene Fluorinations with Diaryliodonium Salts
[Image: see text] For the first time it is shown that exceptionally electron-rich arene rings can be fluorinated exclusively during the reductive elimination reactions of diaryliodonium fluorides. The 5-methoxy[2.2]paracyclophan-4-yl directing group simultaneously reduces unproductive aryne chemistr...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2011
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3126865/ https://ncbi.nlm.nih.gov/pubmed/21591627 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201080c |
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