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Unprecedented Directing Group Ability of Cyclophanes in Arene Fluorinations with Diaryliodonium Salts

[Image: see text] For the first time it is shown that exceptionally electron-rich arene rings can be fluorinated exclusively during the reductive elimination reactions of diaryliodonium fluorides. The 5-methoxy[2.2]paracyclophan-4-yl directing group simultaneously reduces unproductive aryne chemistr...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Graskemper, Joseph W., Wang, Bijia, Qin, Linlin, Neumann, Kiel D., DiMagno, Stephen G.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2011
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3126865/
https://ncbi.nlm.nih.gov/pubmed/21591627
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201080c
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