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Regiospecific reductive elimination from diaryliodonium salts
StereoElectronic Control of Unidirectional Reductive Elimination (SECURE) is provided by the cyclophane substituent on iodine(III). Computational and experimental studies demonstrate that out of plane steric bulk strongly destabilizes the reductive elimination transition state, and leads to regioche...
Tallennettuna:
| Päätekijät: | , , , |
|---|---|
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2010
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3498817/ https://ncbi.nlm.nih.gov/pubmed/20425876 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201000695 |
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