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Fluoride-Promoted Ligand Exchange in Diaryliodonium Salts

Diaryliodonium salts are shown to undergo rapid, fluoride-promoted aryl exchange reactions at room temperature in acetonitrile. Aryl exchange is shown to be exquisitely sensitive to the concentration of fluoride ion in solution; fast exchange is observed as the fluoride concentration approaches a st...

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Main Authors: Wang, Bijia, Cerny, Ronald L., Uppaluri, ShriHarsha, Kempinger, Jayson J., DiMagno, Stephen G.
Format: Artigo
Jezik:Inglês
Izdano: 2010
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2967785/
https://ncbi.nlm.nih.gov/pubmed/21057607
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jfluchem.2010.04.004
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