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N-Allyl-N-Sulfonyl Ynamides as Synthetic Precursors to Amidines and Vinylogous Amidines. An Unexpected N-to-C 1,3-Sulfonyl Shift in Nitrile Synthesis

[Image: see text] A detailed study of amidine synthesis from N-allyl-N-sulfonyl ynamides is described here. Mechanistically, this is a fascinating reaction consisting of diverging pathways that could lead to deallylation or allyl transfer depending upon the oxidation state of palladium catalysts, th...

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Библиографические подробности
Главные авторы: DeKorver, Kyle A., Johnson, Whitney L., Zhang, Yu, Hsung, Richard P., Dai, Huifang, Deng, Jun, Lohse, Andrew G., Zhang, Yan-Shi
Формат: Artigo
Язык:Inglês
Опубликовано: 2011
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC3120114/
https://ncbi.nlm.nih.gov/pubmed/21563776
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo200780x
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