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The Effects of Non-Redox Active Metal Ions on the Activation of Dioxygen: Isolation and Characterization of a Heterobimetallic Complex Containing a Mn(III)–(μ-OH)–Ca(II) core
Rate enhancements for the reduction of dioxygen by a Mn(II) complex were observed in the presence of redox inactive Group 2 metal ions. The rate changes correlated with an increase in the Lewis acidity of the Group 2 metal ions. These studies led to the isolation of heterobimetallic complexes that c...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3116078/ https://ncbi.nlm.nih.gov/pubmed/21595481 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja203458d |
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