Models for Unsymmetrical Active Sites in Metalloproteins: Structural, Redox, and Magnetic Properties of Bimetallic Complexes with M(II)–(μ-OH)–Fe(III) Cores

Bimetallic complexes are important sites in metalloproteins but are often difficult to prepare synthetically. We have previously introduced an approach to form discrete bimetallic complexes with M(II)–(μ-OH)–Fe(III) (M(II) = Mn, Fe) cores using the tripodal ligand N,N′,N″-[2,2′,2″-nitrilotris(ethane...

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Bibliographic Details
Published in:	Inorg Chem
Main Authors:	Sano, Yohei, Lau, Nathanael, Weitz, Andrew C., Ziller, Joseph W., Hendrich, Michael P., Borovik, A.S.
Format:	Artigo
Language:	Inglês
Published:	2017
Subjects:	Article
Online Access:	https://ncbi.nlm.nih.gov/pmc/articles/PMC5696092/ https://ncbi.nlm.nih.gov/pubmed/29112385 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b02230
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Models for Unsymmetrical Active Sites in Metalloproteins: Structural, Redox, and Magnetic Properties of Bimetallic Complexes with M(II)–(μ-OH)–Fe(III) Cores

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