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Heterobimetallic Complexes with M(III)-(μ-OH)-M(II) Cores (M(III) = Fe, Mn, Ga; M(II) = Ca, Sr, and Ba): Structural, Kinetic, and Redox Properties
The effects of redox-inactive metal ions on dioxygen activation were explored using a new Fe(II) complex containing a tripodal ligand with 3 sulfonamido groups. This iron complex exhibited a faster initial rate for the reduction of O(2) than its Mn(II) analog. Increases in initial rates were also ob...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3777273/ https://ncbi.nlm.nih.gov/pubmed/24058726 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC21400H |
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