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Isolation and Characterization of a Dihydroxo-Bridged Iron(III,III)(μ-OH)(2) Diamond Core Derived from Dioxygen
Dioxygen addition to coordinatively unsaturated [Fe(II)(O(Me2)N(4)(6-Me-DPEN))](PF(6)) (1) is shown to afford a complex containing a dihydroxo-bridged Fe(III)(2)(μ-OH)(2) diamond core, [Fe(III)(O(Me2)N(4)(6-Me-DPEN))](2)(μ-OH)(2)(PF(6))(2)•(CH(3)CH(2)CN)(2) (2). The diamond core of 2 resembles the o...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3885352/ https://ncbi.nlm.nih.gov/pubmed/24229319 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic4010906 |
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