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Enantioselective Organocatalytic α-Fluorination of Cyclic Ketones

The first highly enantioselective α-fluorination of ketones using organocatalysis has been accomplished. The long-standing problem of enantioselective ketone α-fluorination via enamine activation has been overcome via high-throughput evaluation of a new library of amine catalysts. The optimal system...

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Detalhes bibliográficos
Main Authors: Kwiatkowski, Piotr, Beeson, Teresa D., Conrad, Jay C., MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3107934/
https://ncbi.nlm.nih.gov/pubmed/21247133
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja111163u
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