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Stereoselective Synthesis of a Model C(18)–C(35) Spiroketal Fragment of Integramycin
[Image: see text] A highly stereoselective synthesis of a model C(18)–C(35) spiroketal unit (7) of integramycin has been accomplished via an enantioselective stannyl-crotylboration reaction and an N-iodosuccinimide-mediated spiroketalization of 19a.
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2011
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3094501/ https://ncbi.nlm.nih.gov/pubmed/21510632 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol200834p |
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