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Gold-Catalyzed Nitrene Transfer to Activated Alkynes: Formation of α, β-Unsaturated Amidines
[Image: see text] A gold-catalyzed intermolecular nitrene transfer to alkynes was developed for the first time, revealing a new mode of nitrene transfer and providing a novel access to versatile α-imino metal carbenes. Various mild nitrene-transfer reagents were examined, and iminopyridium ylides es...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3085905/ https://ncbi.nlm.nih.gov/pubmed/21351760 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol2002607 |
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