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Gold-Catalyzed Highly Regioselective Oxidation of C-C Triple Bonds Without Acid Additives: Propargyl Moieties as Masked α,β-Unsaturated Carbonyls

Gold-catalyzed intermolecular oxidations of internal alkynes have been achieved with high regioselectivities using 8-alkylqinoline N-oxides as oxidants and in the absence of acid additives. Synthetically versatile α,β-unsaturated carbonyls are obtained in good to excellent yields and with excellent...

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Main Authors: Lu, Biao, Li, Chaoqun, Zhang, Liming
格式: Artigo
語言:Inglês
出版: 2010
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2978523/
https://ncbi.nlm.nih.gov/pubmed/20853846
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1072614
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