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Correlation of the Rates of Solvolysis of Neopentyl Chloroformate—A Recommended Protecting Agent

The specific rates of solvolysis of neopentyl chloroformate (1) have been determined in 21 pure and binary solvents at 45.0 °C. In most solvents the values are essentially identical to those for ethyl and n-propyl chloroformates. However, in aqueous-1,1,1,3,3,3-hexafluoro-2-propanol mixtures (HFIP)...

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Detalhes bibliográficos
Main Authors: D’Souza, Malcolm J., Carter, Shannon E., Kevill, Dennis N.
Formato: Artigo
Idioma:Inglês
Publicado em: Molecular Diversity Preservation International (MDPI) 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3083697/
https://ncbi.nlm.nih.gov/pubmed/21541050
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms12021161
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