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A Study of Solvent Effects in the Solvolysis of Propargyl Chloroformate

The specific rates of solvolysis of propargyl chloroformate (1) are analyzed in 22 solvents of widely varying nucleophilicity and ionizing power values at 25.0°C using the extended Grunwald-Winstein equation. Sensitivities to solvent nucleophilicity (l) of 1.37 and to solvent ionizing power (m) of 0...

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Autori principali: D'Souza, Malcolm J., Darrington, Anthony M., Kevill, Dennis N.
Natura: Artigo
Lingua:Inglês
Pubblicazione: International Scholarly Research Network 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3111911/
https://ncbi.nlm.nih.gov/pubmed/21666878
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.5402/2011/767141
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