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A Study of Solvent Effects in the Solvolysis of Propargyl Chloroformate
The specific rates of solvolysis of propargyl chloroformate (1) are analyzed in 22 solvents of widely varying nucleophilicity and ionizing power values at 25.0°C using the extended Grunwald-Winstein equation. Sensitivities to solvent nucleophilicity (l) of 1.37 and to solvent ionizing power (m) of 0...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
International Scholarly Research Network
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3111911/ https://ncbi.nlm.nih.gov/pubmed/21666878 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.5402/2011/767141 |
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