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Correlation of the Rates of Solvolysis of Neopentyl Chloroformate—A Recommended Protecting Agent

The specific rates of solvolysis of neopentyl chloroformate (1) have been determined in 21 pure and binary solvents at 45.0 °C. In most solvents the values are essentially identical to those for ethyl and n-propyl chloroformates. However, in aqueous-1,1,1,3,3,3-hexafluoro-2-propanol mixtures (HFIP)...

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Bibliografische gegevens
Hoofdauteurs: D’Souza, Malcolm J., Carter, Shannon E., Kevill, Dennis N.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Molecular Diversity Preservation International (MDPI) 2011
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3083697/
https://ncbi.nlm.nih.gov/pubmed/21541050
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms12021161
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