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Correlation of the Rates of Solvolysis of Neopentyl Chloroformate—A Recommended Protecting Agent

The specific rates of solvolysis of neopentyl chloroformate (1) have been determined in 21 pure and binary solvents at 45.0 °C. In most solvents the values are essentially identical to those for ethyl and n-propyl chloroformates. However, in aqueous-1,1,1,3,3,3-hexafluoro-2-propanol mixtures (HFIP)...

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Autori principali: D’Souza, Malcolm J., Carter, Shannon E., Kevill, Dennis N.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Molecular Diversity Preservation International (MDPI) 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3083697/
https://ncbi.nlm.nih.gov/pubmed/21541050
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms12021161
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