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Oxidative allylic rearrangement of cycloalkenols: Formal total synthesis of enantiomerically pure trisporic acid B

Enantiomerically highly enriched unsaturated β-ketoesters bearing a quaternary stereocenter can be utilized as building blocks for the synthesis of natural occurring terpenes, i. a., trisporic acid and its derivatives. An advanced building block has been synthesized in a short reaction sequence, whi...

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Autors principals: Dubberke, Silke, Abbas, Muhammad, Westermann, Bernhard
Format: Artigo
Idioma:Inglês
Publicat: Beilstein-Institut 2011
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3079125/
https://ncbi.nlm.nih.gov/pubmed/21512603
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.54
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