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A Formal Rearrangement of Allylic Silanols
We show that 1M aqueous HCl/THF or NaBH(4)/DMF allows for demercurative ring-opening of cyclic organomercurial synthons into secondary silanol products bearing terminal alkenes. We had previously demonstrated that primary allylic silanols are readily transformed into cyclic organomercurials using Hg...
Tallennettuna:
| Julkaisussa: | Molecules |
|---|---|
| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
MDPI
2021
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8270268/ https://ncbi.nlm.nih.gov/pubmed/34201779 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26133829 |
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