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On the Stereochemistry of 2-Hydroxyethylphosphonate Dioxygenase
[Image: see text] Stereochemical investigations have shown that the conversion of 2-hydroxyethylphosphonate to hydroxymethylphosphonate by the enzyme HEPD involves removal of the pro-S hydrogen at C2 and, surprisingly, the loss of stereochemical information at C1. As a result, the mechanisms previou...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American Chemical Society
2011
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| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3069692/ https://ncbi.nlm.nih.gov/pubmed/21381767 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1113326 |
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