The Stereoselective Formation of Bicyclic Enamines with Bridgehead Unsaturation via Tandem C-H Bond Activation/Alkenylation/Electrocyclization

[Image: see text] Bridgehead bicyclic unsaturated enamines were prepared by a tandem rhodium-catalyzed C-H bond activation/alkenylation/electrocyclization of alkyne-tethered unsaturated imines. These strained bicyclic enamines exhibit unique reactivity: for example, they give N-Alkylated products up...

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Autores principales: Yotphan, Sirilata, Bergman, Robert G., Ellman, Jonathan A.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2008
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3062933/
https://ncbi.nlm.nih.gov/pubmed/18247623
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja710981b
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