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Rhodium(III)-catalyzed C–H functionalization of C-alkenyl azoles with sulfoxonium ylides for the synthesis of bridgehead N-fused [5,6]-bicyclic heterocycles

The synthesis of bridgehead N-fused [5,6]-bicyclic heterocycles via rhodium(III)-catalyzed C–H functionalization of C-alkenyl azoles with sulfoxonium ylides is disclosed. Reactions proceeded in good to high yields for a range of aryl, heteroaryl and alkyl sulfoxonium ylides. In addition, 2-alkenyl i...

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Detalhes bibliográficos
Publicado no:Tetrahedron
Main Authors: Hoang, Gia L., Ellman, Jonathan A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6034689/
https://ncbi.nlm.nih.gov/pubmed/29988985
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2018.03.062
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