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Stereoselective Alkylation of α,β-Unsaturated Imines via C-H Bond Activation

[Image: see text] The stereoselective alkylation of α,β-unsaturated imines via C-H activation followed by imine hydrolysis produces tri- and tetrasubstituted α,β-unsaturated aldehydes. In the presence of a rhodium catalyst, α,β-unsaturated N-benzyl imines derived from methacrolein, crotonaldehyde, a...

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Detalhes bibliográficos
Main Authors: Colby, Denise A., Bergman, Robert G., Ellman, Jonathan A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2585547/
https://ncbi.nlm.nih.gov/pubmed/16637605
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0584931
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