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Rhodium(III) Catalyzed Arylation of Boc-Imines via C–H Bond Functionalization

The first rhodium catalyzed arylation of imines proceeding via C–H bond functionalization is reported. Use of a non-coordinating halide abstractor is important to obtain reactivity. Aryl branched N-Boc-amines are formed and a wide range of functionality is compatible with the reaction.

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Detalhes bibliográficos
Main Authors: Tsai, Andy S., Tauchert, Michael E., Bergman, Robert G., Ellman, Jonathan A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3045530/
https://ncbi.nlm.nih.gov/pubmed/21204527
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja109562x
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