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Mechanism of the Rhodium(III)-Catalyzed Arylation of Imines via C–H Bond Functionalization: Inhibition by Substrate

Rh(III)-catalyzed arylation of imines provides a new method for C–C bond formation, while simultaneously introducing an α-branched amine as a functional group. A detailed mechanistic study provides insights for the rational future development of this new reaction. Relevant intermediate Rh(III)-compl...

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Detalhes bibliográficos
Main Authors: Tauchert, Michael E., Incarvito, Christopher D., Rheingold, Arnold L., Bergman, Robert G., Ellman, Jonathan A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3269099/
https://ncbi.nlm.nih.gov/pubmed/22257031
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211110h
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