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Oxidative group transfer to a triiron complex to form a nucleophilic μ(3)-nitride, [Fe(3)(μ(3)-N)](−)
Utilizing a hexadentate ligand platform, a high-spin trinuclear iron complex of the type ((tbs)L)Fe(3)(thf) was synthesized and characterized ([(tbs)L](6−) = [1,3,5-C(6)H(9)(NPh-o-NSi(t)BuMe(2))(3)](6−)). The silyl-amide groups only permit ligation of one solvent molecule to the tri-iron core, resul...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3056537/ https://ncbi.nlm.nih.gov/pubmed/21332160 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2003445 |
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