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Mechanism of methanol oxidation by quinoprotein methanol dehydrogenase
At neutral pH, oxidation of CH(3)OH → CH(2)O by an o-quinone requires general-base catalysis and the reaction is endothermic. The active-site –CO(2)(−) groups of Glu-171 and Asp-297 (Glu-171–CO(2)(−) and Asp-297–CO(2)(−)) have been considered as the required general base catalysts in the bacterial o...
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| 主要な著者: | , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
National Academy of Sciences
2007
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3020142/ https://ncbi.nlm.nih.gov/pubmed/17215371 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0610126104 |
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