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Conformation of coenzyme pyrroloquinoline quinone and role of Ca(2+) in the catalytic mechanism of quinoprotein methanol dehydrogenase

The ab initio structures of 2,7,9-tricarboxypyrroloquinoline quinone (PQQ), semiquinone (PQQH), and dihydroquinone (PQQH2) have been determined and compared with ab initio structures of the (PQQ)Ca(2+), (PQQH)Ca(2+), and (PQQH2)Ca(2+) complexes as well as the x-ray structure of (PQQ)Ca(2+) bound at...

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Библиографические подробности
Главные авторы: Zheng, Ya-Jun, Bruice, Thomas C.
Формат: Artigo
Язык:Inglês
Опубликовано: The National Academy of Sciences of the USA 1997
Предметы:
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC23644/
https://ncbi.nlm.nih.gov/pubmed/9342331
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