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Conformation of coenzyme pyrroloquinoline quinone and role of Ca(2+) in the catalytic mechanism of quinoprotein methanol dehydrogenase
The ab initio structures of 2,7,9-tricarboxypyrroloquinoline quinone (PQQ), semiquinone (PQQH), and dihydroquinone (PQQH2) have been determined and compared with ab initio structures of the (PQQ)Ca(2+), (PQQH)Ca(2+), and (PQQH2)Ca(2+) complexes as well as the x-ray structure of (PQQ)Ca(2+) bound at...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
The National Academy of Sciences of the USA
1997
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC23644/ https://ncbi.nlm.nih.gov/pubmed/9342331 |
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