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Asymmetric Synthesis of All the Known Phlegmarine Alkaloids
The asymmetric synthesis of all four of the known natural phlegmarines and one synthetic derivative has been accomplished in 19 to 22 steps from 4-methoxy-3-(triisopropylsilyl)pyridine. Chiral N-acylpyridinium salt chemistry was used twice to set the stereocenters at the C-9 and C-2′ positions of th...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3006060/ https://ncbi.nlm.nih.gov/pubmed/21077636 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo1019688 |
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