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Synthetic Utility of Epoxides for Chiral Functionalization of Isoxazoles

The lithio-anion of isoxazole 2 was found to ring open propylene oxide in good yields with complete regioselectivity. Vinylic and benzylic epoxides were utilized as key examples of electrophiles and found to produce a mixture of regioisomeric adducts. Additionally, the use of chiral epoxides was exp...

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Detalhes bibliográficos
Main Authors: Nelson, Jared K., Burns, Christopher T., Smith, Miles P., Twamley, Brendan, Natale, N. R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2988249/
https://ncbi.nlm.nih.gov/pubmed/21103024
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.03.059
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