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Hydride-Containing Models for the Active Site of the Nickel-Iron Hydrogenases
The [NiFe]-hydrogenase model complex NiFe(pdt)(dppe)(CO)(3) (1) (pdt = 1,3-propanedithiolate) has been efficiently synthesized and found to be robust. This neutral complex sustains protonation to give the first nickel-iron hydride [1H]BF(4). One CO ligand in [1H]BF(4) is readily substituted by organ...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2980840/ https://ncbi.nlm.nih.gov/pubmed/20925337 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105312p |
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