Loading...
Hydride-Containing Models for the Active Site of the Nickel-Iron Hydrogenases
The [NiFe]-hydrogenase model complex NiFe(pdt)(dppe)(CO)(3) (1) (pdt = 1,3-propanedithiolate) has been efficiently synthesized and found to be robust. This neutral complex sustains protonation to give the first nickel-iron hydride [1H]BF(4). One CO ligand in [1H]BF(4) is readily substituted by organ...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2010
|
| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2980840/ https://ncbi.nlm.nih.gov/pubmed/20925337 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105312p |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|