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Hydride-Containing Models for the Active Site of the Nickel-Iron Hydrogenases

The [NiFe]-hydrogenase model complex NiFe(pdt)(dppe)(CO)(3) (1) (pdt = 1,3-propanedithiolate) has been efficiently synthesized and found to be robust. This neutral complex sustains protonation to give the first nickel-iron hydride [1H]BF(4). One CO ligand in [1H]BF(4) is readily substituted by organ...

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書誌詳細
主要な著者: Barton, Bryan E., Rauchfuss, Thomas B.
フォーマット: Artigo
言語:Inglês
出版事項: 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2980840/
https://ncbi.nlm.nih.gov/pubmed/20925337
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105312p
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