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Allylic C–H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy to Achieve Aerobic Catalytic Turnover
Pd-catalyzed C–H oxidation reactions often require the use of oxidants other than O(2.) Here, we demonstrate a ligand-based strategy to replace benzoquinone with O(2) as the stoichiometric oxidant in Pd-catalyzed allylic C–H acetoxylation. Use of 4,5-diazafluorenone (1) as an ancillary ligand for Pd...
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| Hauptverfasser: | , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2010
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2971663/ https://ncbi.nlm.nih.gov/pubmed/20929224 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105829t |
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