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Stereospecificity of the Dehydratase Domain of the Erythromycin Polyketide Synthase

[Image: see text] The dehydratase (DH) domain of module 4 of the 6-deoxyerythronolide B synthase (DEBS) has been shown to catalyze an exclusive syn elimination/syn addition of water. Incubation of recombinant DH4 with chemoenzymatically prepared anti-(2R,3R)-2-methyl-3-hydroxypentanoyl-ACP (2a-ACP)...

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Autors principals: Valenzano, Chiara R., You, Young-Ok, Garg, Ashish, Keatinge-Clay, Adrian, Khosla, Chaitan, Cane, David E.
Format: Artigo
Idioma:Inglês
Publicat: 2010
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2959128/
https://ncbi.nlm.nih.gov/pubmed/20925342
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja107344h
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