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An Approach Toward Oxidopyrylium Ylides Using Rh(II)-Catalyzed Cyclization Chemistry

The Rh(II)-catalyzed reaction of the E-isomer of 2-diazo-3,6-dioxo-6-phenyl-hex-enoic acid methyl ester was carried out in the presence of various carbonyl compounds and was found to give 1,3-dioxoles in moderate to good yield. In an attempt to prepare the starting -diazo substrate, an unexpected ps...

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Detalhes bibliográficos
Main Authors: Padwa, Albert, Boonsombat, Jutatip, Rashatasakhon, Paitoon
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2955265/
https://ncbi.nlm.nih.gov/pubmed/20953288
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2007.06.118
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