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Synthesis of (±)-3H-epivincamine via a Rh(II)-Triggered Cyclization/Cycloaddition Cascade
A synthesis of (±)-3H-epivincamine is reported. Important steps include: (1) a Rh(II)-catalyzed intramolecular [3+2]-cycloaddition of an α-diazo indolo amide; (2) a reductive ring opening of the cycloadduct; (3) a decarboethoxylation reaction; and (4) a base-induced keto-amide ring contraction.
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| Main Authors: | , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2007
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2587099/ https://ncbi.nlm.nih.gov/pubmed/17658832 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol071173x |
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