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Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex

We report a rhodium catalyst that exhibits high reactivity for the hydroamination of primary aminoalkenes that are unbiased toward cyclization and that possess functional groups that would not be tolerated in hydroaminations catalyzed by more electrophilic systems. This catalyst contains an unusual...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Julian, Lisa D., Hartwig, John F.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2010
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2948069/
https://ncbi.nlm.nih.gov/pubmed/20839807
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1052126
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